Beilstein J. Org. Chem.2017,13, 2486–2501, doi:10.3762/bjoc.13.246
probed by DFT calculations.
Keywords: chlorination; copper mediated perfluoroalkylation; crystal structure; DFT calculations; fluorous; hypervalent iodine; nucleophilic substitution; polarspacegroup; Introduction
A number of fluorous alkyl iodides, usually of the formula RfnCH2CH2I or RfnI (Rfn = CF3
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Graphical Abstract
Scheme 1:
Some previously reported iodine(III) dichlorides relevant to this work.